Regularized resolvent transform for direct calculation of 45 degrees projections of 2D J spectra.

Armstrong GS, Chen J, Cano KE, Shaka AJ, Mandelshtam VA.

Department of Chemistry, University of California, Irvine, CA 92697-2025, USA.


The regularized resolvent transform (RRT) has been applied in a novel way to J-resolved spectra. This involves the direct calculation of the 45 degrees projection without constructing the 2D spectrum. The results show a significant resolution enhancement over that obtained by the 45 degrees projection of a 2D Fourier spectrum, even for much larger signals. In particular, RRT is able to resolve peaks that belong to different overlapping multiplets in a very crowded spectral region, where the conventional technique fails for any signal size. The resolving power of this method along with the significantly shorter signals required, make this method a powerful tool in spectral assignment.