47)“The Putidaredoxin Reductase-Putidaredoxin Electron Transfer Complex: Theoretical and Experimental Study” Kuznetsov, V. Y.; Blair, E.; Farmer, P. J.; Poulos, T.L.; Pifferitti, A.; Sevrioukova, I.F. J. Biol. Chem. 2005, 280, 16135-16142.

46) The Effect of Stacking and Redox State on Optical Absorption Spectra of Melanins- a comparison of theoretical and experimental results.” Stark, K.B.; Gallas, J.M.; Zajac G.W.; Golab, J.T.; Gidanian, S.; McIntire, T.; Farmer, P.J. J. Phys. Chem. B. 2005,109, 1970-1977. (ref)

45) “Bonding in HNO-Myoglobin as Characterized by X-Ray Absorbance and Resonance Raman Spectroscopies” Immoos, C.E.; Sulc, F.; Farmer, P.J.; Czarnecki, K.; Bocian, D.F.; Levina, A.; Aitken, J.B.; Armstrong, R.S.; Lay, P.A. J. Am. Chem. Soc. 2005, 127, 814 – 815.(ref)

44) “Coordination Chemistry of the HNO Ligand with Hemes and Synthetic Coordination Complexes” Farmer, P.J.; Sulc, F. J. Inorg. Biochem. 2005, 99, 166-184.(ref)

43) “Multiple pathways for the oxygenation of a Ru(II) dithiocarbamate complex: S-Oxygenation and S-Extrusion” Ng, S.;  Ziller, J.;  Farmer, P.J. Inorg. Chem. 2004, 43, 8301-8309.(ref)

42) “Disulfiram causes intracellular Cu uptake and induces apoptosis in human melanoma cells” Cen, D.; Brayton, D.; Shahandeh, B.; Meyskens, F.L.; Farmer, P.J. J. Med. Chem. 2004, 47, 6914 - 6920. (ref)

41) “High Temperature Electrocatalysis Using Thermophilic P450 CYP119: Dehalogenation of CCl₄ to CH₄” Blair, E.; Greaves, J.; Farmer, P.J. J. Am. Chem. Soc. 2004, 126, 8632-8633.(ref)

40) “Electron Transfer Chemistry of Ru-linker-(heme)-modified Myoglobin: Rapid Intraprotein Reduction of a Photogenerated Porphyrin Cation Radical” Immoos, C.E.; Di Bilio, A.J.; Cohen, M.S.; Van der Veer, W.; Gray, H.B.; Farmer, P.J. Inorg. Chem. 2004, 43, 3593 – 3596. (ref)

39) “Electrocatalytic reductions of nitrite, nitric oxide and nitrous oxide by Cytochrome P450 CYP 119”  Immoos, C.E.; Chou, J.; Bayachou, M.; Blair, E.; Farmer, P.J. J. Am. Chem. Soc. 2004, 126, 4934-4942. (ref)

38) “Etiologic Pathogenesis of Melanoma: A Unifying Hypothesis for the Missing Attributable Risk” Meyskens, F.L.; Farmer, P.J.; Anton-Culver, H. Clin. Canc.  Res.  2004, 10, 2581-2583.

37) “Trapping of Nitroxyl by Deoxy Myoglobin” Sulc, F.; Immoos, C.; Pervitsky, D. Farmer, P.J.  J. Amer. Chem. Soc. 2004, 125, 1096-1101. (ref)

36) “Melanin as a target for melanoma chemotherapy: pro-oxidant effect of oxygen and metals on melanoma viability.” Farmer, P.J.; Gidanian, S.; Shahandeh, B.; Di Bilio, A.J.; Tohidian, N.; Meyskens, F.L.; Pigment Cell. Res. 2003, 16, 273-279. (ref)

35) “A Novel Heme and Peroxide-Dependent Tryptophan-Tyrosine Cross-link in a Mutant of Cytochrome c Peroxidase” Bhaskar, B.; Immoos, C.E.; Shimizu, H.; Sulc, F.; Farmer, P.J.; Poulos, T.L. J. Mol. Biol. 2003, 328, 157-166. (ref)

34) "¹H NMR Structure of the Heme Pocket of HNO-Myoglobin" Sulc, F.; Fleischer, E.; Farmer, P.J.; Ma, D.; La Mar, G. J. Biol. Inorg. Chem. 2003, 8, 348-352. (ref)

33) "Direct Assessment of the Reduction Potential of the [4Fe-4S]^1+/0 Couple of the Nitrogenase Fe Protein from Azotobacter vinelandii”  Guo, M.; Sulc, F.; Ribbe, M.W.; Immoos, C.E.; Farmer, P.J.; Burgess, B.K. J. Amer. Chem. Soc. 2002, 124, 2100-12101. (ref)

32) "The reduction potential of nitric oxide (NO) and its importance to NO biochemistry" Bartberger, M.D.; Liu, W.; Ford, E.; Miranda, K.M.;  Switzer, C.; Fukuto, J.M.; Farmer, P.J.; Wink, D.A.; Houk K. N. Proc. Nat. Acad. Sci. 2002, 99, 10958-10963.(ref)

31) "Mesopone Cytochrome C Peroxidase: Functional Model of Heme Oxygenated Oxidases" Immoos, C.E.; Bhaskar, B.; Cohen, M.S.; Barrows, T.P.; Farmer^, P.J.; Poulos, T.L.  J. Inorg. Biochem. 2002, 91, 635-643.(ref)

30) “Enhanced electron transfer and lauric acid hydroxylation by site-directed mutagenesis of CYP119” Koo, L.S.; Immoos, C.E.; Cohen, M.S.; Farmer, P.J.; de Montellano, P.R.O. J. Am. Chem. Soc. 2002, 124, 5684-5691. (ref)

29) "Redox Behavior of Melanins: Direct Electrochemistry of DHI-melanin and its Cu and Zn Adducts " Gidanian, S.; Farmer, P.J. J. Inorg. Biochem. 2002, 89, 54-60.

28) "Metal Binding by Melanins: Studies of Colloidal DHI-Melanin, and its Complexation by Cu(II), and Zn(II) Ions " Szpoganicz, B.; Gidanian, S.;  Kong, P.; Farmer, P.J J. Inorg. Biochem. 2002, 89, 45-53.

27) “The influence of b- and g-Cyclodextrin cavity size on the association constant with Decanoate and Octanoate anions” Meier, M.M.; Bordignon-Luiz, M.T.; Farmer, P.J.; Szpoganicz, B. J. Inclusion Phenomena  2001, I, 291-295.

26) “Redox Regulation in Human Melanocytes and Melanoma” Meyskens, F.L.; Farmer, P.J.; Fruehauf, J. Pigment Cell Res., 2001, 14, 148-154.

25) "O-Atom Transfer from Nitric Oxide Catalyzed by Fe(TPP)" Lin, R.; Farmer, P.J.  J. Am. Chem. Soc. 2001, 123, 1143 -1150. (ref)

24) “Unusual voltammetry of manganese-substituted myoglobin in surfactant film: evidence for two redox pathways” Lin, R.; Immoos, C.; Farmer, P.J. J. Biol. Inorg. Chem. 2000, 5, 738-747.

23) “Electron Transfer in the Ruthenated Heme Domain of Cytochrome P450BM-3” Sevrioukova, I.F.; Immoos, C.E.; Poulos, T.L.; Farmer, P.J. Isr. J. Chem. 2000, 40, 47-53.

22) “The HNO Adduct of Myoglobin: Synthesis and Characterization” Lin, R.; Farmer, P.J. J. Am. Chem. Soc. 2000, 122, 2393 –2394. (ref)

21) “Catalytic Two-electron Reductions of N₂O and N₃^- by Myoglobin in Surfactant Film” Bayachou, M.; Elkbir, L.; Farmer, P.J. Inorg. Chem. 2000, 39, 289-293. (ref)

20) "AM1-SM2 calculations model the redox potential of nitroxyl radicals such as TEMPO" Rychnovsky, S. D.; Vaidyanathan, R.; Beauchamp, T.; Lin, R.; Farmer, P. J. J. Org. Chem. 1999, 64, 6745-6749.(ref)

19) "Electrochemical Reduction of NO by Myoglobin in Surfactant Film: Characterization and Reactivity of the Nitroxyl (NO-) Adduct" Bayachou, M.; Lin, R.; Cho, W.; Farmer, P. J. J. Am. Chem. Soc. 1998, 120, 9888-9893. (ref)

18) "1,5-Diazacyclooctane, Pendant Arm Thiolato Derivatives and [N,N'Bis(2-Mercaptoethyl)-1,5-Diazacyclooctanato]Nickel(II)" Mills, D.K.; Font, I.; Farmer, P.J.; Hsiao, Y.-M.; Tuntulani, T.; Buonomo, R.M.; Goodman, D.C.; Musie, G.; Grapperhaus, C.A.; Maguire, J.J.; Lai, C.-H.; Hatley, M.L.; Smee, J.J.; Bellefeuille, J.A.; Darensbourg, M.Y. Inorg. Synth. 1998, 32, 89.

 17) “Electrochemistry and catalysis by myoglobin in surfactant films.” Farmer, PJ; Lin, R; Bayachou, M.  Comm. Inorg. Chem. 1998, 20, 101-120.

16) "Nitrite Reduction by Myoglobin in Surfactant Films," Lin, R.; Bayachou, M.; Farmer, P.J. J. Am. Chem. Soc. 1997, 119, 12689-12690. (ref)

15) “A Coordination Polymer of Nickel(II) Based on a Pentadentate N,S, and O donor Ligand” Goodman, D.C.; Farmer, P.J.; Darensbourg, M.Y.; Reibenspies, J.H. Inorg. Chem. 1996, 35, 4989.

14) “Polydentate N₂S₂O and N₂S₂O₂ Ligands as Alcoholic Derivatives of (N,N'-Bis(2-mercaptoethyl)-1,5-diazacycloctane)nickel(II) and of (N,N'-Bis(2-mercapto-92-methylpropane)-1,5-diazacycloctane)nickel(II)” Goodman, D.C.; Buonomo, P.M.; Farmer, P.J.; Reibenspies, J.H.; Darensbourg, M.Y. Inorg. Chem. 1996, 35, 4029.

13) “Intramolecular Electron-Transfer in Cyanide-Bridged Ruthenium Dimers”  Ponce, A.; Bachrach, M.; Farmer, P.J.; Winkler, J.R. Inorg. Chim. Acta  1996, 243, 135.

 12) “Influence of Sulfur Metallation on the Accessibility of the NiII/I Couple in N,N'-Bis[mercaptoethyl]-1,5-diazacyclooctanenickel(II): Insight into the Redox Properties of [NiFe]-Hydrogenase"  Musie, G.; Farmer, P.J.; Tuntulani, T.; Reibenspies, J.H.; Darensbourg, M.Y. Inorg. Chem. 1996, 35, 2176.

11) “Strategies for the Generation of Ferryl Heme Intermediates by Photoinduced Electron Transfer” Berglund, J.; Farmer, P.J.; Low, D.W.; Pascher, T.; Winkler, J.R.; Gray, H.B.  J. Inorg. Biochem.  1995, 59, 467.

10) "Reduction-Promoted Sulfur-Oxygen Bond Cleavage in a Nickel Sulfenate as a Model for the Activation of [NiFe] Hydrogenase"  Farmer, P.J.; Verpequx, J.N.; Amatore, C.; Darensbourg, M.Y.; Musie, G.  J. Am. Chem. Soc.  1994, 116, 9355.

9) “Divergent Pathways for the Addition of Dioxygen to Sulfur in Nickel cis-Dithiolates:  An Isotopomeric Analysis”  Farmer, P.J.; Solouki, T.; Soma, T.; Russell, D.H.; Darensbourg, M.Y.  Inorg. Chem. 1993, 32, 4171.

8)  “The Mechanism of O₂ Addition to Ni-bound Thiolates”  Darensbourg, M.Y.; Farmer, P.J.; Soma, T.; Russell, D.H.;  Solouki, T.; Reibenspies, J.H.  in The Activation of Dioxygen and Homogeneous Catalytic Oxidation;  D.H.R. Barton, A.E. Martell, and D.T. Sawyer, Ed.; Plenum Press: New York, 1993 p. 209-215.

7) "Effects of Sulfur-Site Modification on the Redox Potentials of Derivatives of N,N'-Bis[mercaptoethyl]-1,5-diazacyclooctanenickel(II)"  Farmer, P.J.; Reibenspies, J.H.; Lindahl, P.A.; Darensbourg, M.Y. J. Am. Chem. Soc. 1993, 115, 4665.

6) "Axial Ligation of Diazacyclooctanenickel and -Zinc Complexes"  Goodman, D.C.; Tuntulani, T.; Farmer, P.J.; Darensbourg, M.Y.; Reibenspies, J.H. Angew. Chem. 1993, 32, 116.

5) "Preparation and Structures of a Zinc(II) Dimer and  Zinc(II) Pentanuclear Derivatives of N,N'-Bis(mercaptoethyl)-1,5-diazacycloctane: [(BME-DACO)Zn]₂ and {[(BME-DACO)Ni]₃[ZnCl]₂}{BF₄}₂"  Tuntulani, T.; Reibenspies, J.H.; Farmer, P.J.; Darensbourg, M.Y. Inorg. Chem.  1992, 31, 3497.

4) "Isotopic Labeling Investigation of the Oxygenation of Nickel-Bound Thiolates by Molecular Oxygen"  Farmer, P.J.; Solouki, T.S.; Mills, D.K.; Soma, T.; Russell, D.H.; Reibenspies, J.H.; Darensbourg, M.Y. J. Am. Chem. Soc.  1992, 114, 4601.

3)  "Applications of the N₂S₂ Ligand, N,N'-Bis(mercaptoethyl)-1,5-diazacyclooctane, toward the Formation of Bi- and Heterometallics: [(BME-DACO)Fe]₂ and [(BME-DACO)NiFeCl₂]₂"  Mills, D.K.; Hsiao, Y.M.; Farmer, P.J.; Atnip, E.V.; Reibenspies, J.H.; Darensbourg, M.Y. J. Am. Chem. Soc. 1991, 113, 1421.

2) "Cation-Dependence of the Self-Association Behavior of Guanylyl-(3’-5’)-Guanosine" Walmsley, J.A.; Schneider, M.L.; Farmer, P.J.; Cave, J.R.; Toth, C.R.; Wilson, R.M. J. Biomol. Struct. 1991, 10, 619.

1) "Hydrogen Bonding between Guanosine 5'-Monophosphate and Coordinatively Saturated Cobalt(III) and Platinum (II) Ammine and Ethylenediamine Complex Cations"  Farmer, P.J.; Cave, J.R.; Fletcher, T.M.; Rhubottom, J.A.; Walmsley, J.A. Inorg. Chem.  1991, 30, 3414.